Quick maths help

A question: What is the likelihood of rolling one dice two times and getting a number 4 and a number 5?
I think it's 2 in 36...
either the 4 or 5 in the first roll could be paired with the 5 or 4 from the second roll, 36 possibilities.
but could it be 4 in 12? 6 possibilities first roll, 6 second roll.
I'm sure it's obvious why the (second?) idea is wrong... can anyone explain to me why?
I think it's 2 in 36...
either the 4 or 5 in the first roll could be paired with the 5 or 4 from the second roll, 36 possibilities.
but could it be 4 in 12? 6 possibilities first roll, 6 second roll.
I'm sure it's obvious why the (second?) idea is wrong... can anyone explain to me why?